1)  
How
to export as SYSDBA
          exp
\'sys/pwd as sysdba\'
  2)  Export using parameter file
          exp
parfile=
create a file  exp.par  and insert the following line  and other export parameters
          USERID="sys/
as sysdba" 
To export   a
user must have
CREATE SESSION
EXP_FULL_DATABASE
IMP_FULL_DATABASE
Export utility is created by   CATEXP.SQL
When database is created CATALOG.SQL automatically
runs CATEXP.SQL
 
Tags:
Oracle